Układy nanohybrydowe poliuretan/funkcjonalizowany silseskwioksan. Cz. I, Badania strukturalne z zastosowaniem FT-IR i NMR

B. Janowski; K. Pielichowski

Published : 2012-08-30

Vol. 57 No. 7-8 (2012)

Nanohybrid polyurethane/functionalized silsesquioxane systems. Part I. Structural investigations using FT-IR and NMR methods

B. Janowski K. Pielichowski

Abstract

A chemical structure of polyurethane/functionalized silsesquioxane (PUR/PHIPOSS) nanohybrid materials obtained by prepolymer method has been determined. In the 1H NMR and 13C NMR spectra signals from protons and carbon atoms of the characteristic fragments of the PHIPOSS pendant group have been identified. Analysis of the obtained PUR/PHIPOSS elastomers by ATR-FTIR allowed us to estimate the influence of oligosilsesquioxane side groups on the density of the hydrogen bonds and phase separation. It was found that the degree of phase separation increases with increasing PHIPOSS content.

Keywords

elastomery uretanowe ; funkcjonalizowany silseskwioksan ; materiały nanohybrydowe ; spektroskopia ATR-FTIR ; spektroskopia NMR urethane elastomers ; functionalized silsesquioxane ; nanohybrid materials ; ATR-FTIR spectroscopy ; NMR spectroscopy

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Janowski, B., & Pielichowski, K. (2012). Nanohybrid polyurethane/functionalized silsesquioxane systems. Part I. Structural investigations using FT-IR and NMR methods. Polimery, 57(7-8), 518–528. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/848

References

Kickelbick G.: „Hybrid Materials — Synthesis, Characterization and Applications”, Wiley-VchVerlag, 2007.

2. Peters S. T.: „Handbook of Composites”, 2nd Edition, Chapman & Hall, London 1998.

3. Harper C. A.: „Handbook of Plastics, Elastomers and Composites”, 4th Edition, McGraw-Hill, 2002.

4. Pierson H. O.: „Handbook of Carbon, Graphite, Diamond and Fullerenes—Properties, Processing and Applications”, Noyes Publications, 1993.

5. Lee S. M.: „Handbook of Composite Reinforcements”, Wiley-Vch, 1993.

6. Sanchez C., Soler-Illia G. J. de A. A., Ribot F., Lalot T. i in.: Chem. Mater. 2001, 13, 3061.

7. Florjańczyk Z., Penczek S.: „Chemia Polimerów”, t. III, Oficyna Wydawnicza Politechniki Warszawskiej, Warszawa 1998.

8. Nalwa H. S.: „Handbook of Organic-Inorganic Hybrid Materials and Nanocomposites”, vol. 1, American Scientific Publishers, 2003.

9. Förster S., Plantenberg T.: Angew. Chem. Int. Ed. 2002, 41, 688.

10. Pollet E., Delcourt C., Alexandre M., Dubois P.: Macromol. Chem. Phys. 2004, 205, 2235.

11. Wang H., Zhong W., Xu P., Du Q.: Macromol. Mater. Eng. 2004, 289, 793.

12. Li C. Y., Li L., Cai W., Kodjie S. L. i in.: Adv. Mater. 2005, 17, 1198.

13. Duquesne E., Moins S., Alexandre M., Dubois P.: Macromol. Chem. Phys. 2007, 208, 2542.

14. Karatchevtseva I., Cassidy D. J., Man M. W. C., Mitchell D. R. G. i in.: Adv. Funct. Mater. 2007, 17, 3926.

15. Pagona G., Sandanayaka A. S. D., Araki Y., Fan J. i in.: Adv. Funct. Mater. 2007, 17, 1705.

16. D’Souza F., Chitta R., Sandanayaka A. S. D., Subbaiyan N. K. i in.: Chem. Eur. J. 2007, 13, 8277.

17. Katagiri K., Hashizume M., Ariga K., Terashima T. i in.: Chem. Eur. J. 2007, 13, 5272.

18. Hamurcu E. E., Baysal B. M.: Macromol. Chem. Phys. 1995, 196, 1261.

19. Kickelbick G.: Prog. Polym. Sci. 2003, 28, 83.

20. Schubert U.: J. Sol-Gel Sci. Technol. 2004, 31, 19.

21. Pielichowski K., Njuguna J., Janowski B., Pielichowski J.: Adv. Polym. Sci. 2006, 201, 225.

22. Chang K.-C., Lin C.-Y., Lin H.-F., Chiou S.-C. i in.: J. Appl. Polym. Sci. 2008, 108, 1629.

23. Janowski B., Pielichowski K.: Polimery 2008, 53, 87.

24. Janowski B., Pielichowski K.: J. Organomet. Chem. 2008, 693, 905.

25. Janowski B., Pielichowski K.: Thermochim. Acta. 2008, 478, 51.

26. Lewicki J. P., Pielichowski K., Tremblot De La Croix P., Janowski B. i in.: Polym. Degrad. Stabil. 2010, 95, 1099.

27. Raftopoulos K. N., Pandis Ch., Apekis L., Pissis P. i in.: Polymer 2010, 51, 709.

28. Tien Y. I., Wei K. H.: Polymer 2001, 42, 3213.

29. Król B., Król P.: Polimery 2010, 55, 440.

30. Madbouly S. A., Otaigbe J. U.: Prog. Polym. Sci. 2009, 34, 1283.

31. Kuo S.-W., Chang F.-C.: Prog. Polym. Sci. 2011, 36, 1649.

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