Wybrane zagadnienia pirolizy odpadów tworzyw polimerowych. Cz. I. Problem obecności chloru w oleju pirolitycznym w świetle aktualnego stanu wiedzy

K. German

Published : 2010-05-30

Vol. 55 No. 5 (2010)

Selected problems in the pyrolysis of waste polymers. Part I. The problem related to the presence of chlorine in pyrolytic oils from the view point of the present state of knowledge

K. German

Abstract

The issue of the presence of chlorine in pyrolytic oils obtained from the pyrolysis of municipal waste polymers (MWP) has been discussed based on a review of the literature. The depending factors of the type and amount of chloroorganic compounds in the waste polymer decomposition products containing various amounts of polymers were discussed taking into consideration the presence in them of polyvinyl chloride (Table 2, Fig. 2). A MWP recycling method was proposed with regards to the initial segregation of the polymer content of the wastes according to the density (Table 1). A method for the bonding of the chlorin from chloroorganic compounds using hydrogen, metal oxides, sodium, mixed oxides and iron chloride/carbon systems was described. An analysis of the literature reveals that an effective and cost-efficient method for the elimination of chlorine from pyrolytic oils suitable for industrial scale application has not been presented.

Keywords

piroliza ; odpady tworzyw polimerowych ; odchlorowanie oleju pirolitycznego pyrolysis ; waste polymers ; dechlorinization of pyrolytic oils

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

German, K. (2010). Selected problems in the pyrolysis of waste polymers. Part I. The problem related to the presence of chlorine in pyrolytic oils from the view point of the present state of knowledge. Polimery, 55(5), 351–357. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1015

References

Selected:[1] Kaminsky W., Menzel J., Sinn H.: Conserv. Recycl. 1976, 1, 91.

[2] Kastner H., Kaminsky W.: Hydrocarbon Process. Int. Ed. 1995, 5, 109.

[3] Bockhorn H., Hornung A., Hornung U.: „Gestufte Pyrolyse als Verfahrensprinzip zur chemischen Auftrennung von Kunststoffgemischen“, DECHEMA Ann. Conf., Wiesbaden 1995, mat. konf. vol. 2, str. 270.

[4] Tille A., Derdulla H.-J., Knebel H., Richter M.: Chem. Tech. 1995, 47, nr 4, 190.

[5] Gebauer M., Schermaul D., Timm D.: Chem. Tech. 1995, 47, nr 4, 195.

[6] Nakamura I., Fujimoto K.: Catal. Today 1996, 29, 175.

[7] Zhibo Z., Nishio S., Morioka Y., Ueno A., Ohkita H., Tochihara Y., Mizushima T., Kakuta N.: Catal. Today 1996, 29, 303.

[8] Sasse F., Emig G.: Chem. Eng. Technol. 1998, 21, nr 10, 779.

[9] Ondruschka B., Struppe H. G., Hofmann J., Luther U., Ahlheim J., Gebauer M., Timm D.: Chem. Tech. 1995, 47, nr 4, 171.

[10] Williams E. A., Williams P. T.: J. Chem. Technol. Biotechnol, 1997, 70, 9.

[11] Kaminsky W., Sinn H., Janning J.: Chem. Ing. Tech. 1979, 51, nr 5, 419.

[12] Tukker A., de Groot H., Simons L., Wiegersma S.: “Chemical Recycling of Plastics Waste (PVC and other Resins)”, TNO Report STB-99-55, Final, TNO Institute of Strategy, Technology and Policy, December 1999.

[13] Akimoto M., Ishikawa M., Sato M., Washio K.: J. Chem. Eng. Jpn. 2003, 8, 991.

[14] Hinz B., Hoffmockel M., Pohlmann K., Schädel S., Schimmel I., Sinn H.: J. Anal. Appl. Pyrolysis 1994, 30, 35.

[15] Anonim: Europ. Chem. News 2004, 80, nr 2093, 16.

[16] http://chemie.fb2.fh-frankfurt.de/KUT/Eigenschaften/KU-Eigenschaften.htm

[17] German K., Pielichowski J., Pielichowski K.: „Nowa technologia odpadów tworzyw sztucznych zawierających chlor”, Sprawozdanie PB/71/S2/94/06, 1997.

[18] Miranda R., Pakdel H., Roy C., Darmstadt H., Vasile C.: Polym. Degrad. Stab. 1999, 66, 107.

[19] Sorell G.: Mater. High Temp. 1997, 14, nr 3, 207.

[20] German K.: Czasopismo Techniczne PK, Seria Środowisko 2004, 8, 99.

[21] Miranda R., Pakdel H., Roy C., Vasile C.: Polym. Degrad. Stab. 2001, 73, 47.

[22] Bhaskar T., Uddin Md. A., Murai K., Kaneko J., Hamano K., Kusaba T., Muto A., Sakata Y.: J. Anal. Appl. Pyrolysis 2003, 70, 579.

[23] Miskolczi N., Bartha L., Dea'k G., Jover B.: Polym. Degrad. Stab. 2004, 86, 357

[24] Lingaiah N., Uddin Md. A., Muto A., Imai T., Sakata Y.: Fuel 2001, 80, nr 13, 1901.

[25] Fitko H., Sobolewski A., Burchan M., Gnys J., Makowski A.: Problemy Ekologii 1998, 4, 130.

[26] Müller J., Dongmann G., Frischkorn C. G. B.: J. Anal. Appl. Pyrolysis 1997, 43, 157.

[27] Lingaiah N., Uddin Md A., Muto A., Sakata Y., Imai T., Murata K.: Appl. Catal. A: 2001, 207, nr 1/2, 79.

[28] Brebu M., Bhaskar T., Murai K., Muto A., Sakata Y., Uddin Md. A.: Polym. Degrad. Stab. 2005, 87, 225.

[29] Bhaskar T., Kaneko J., Muto A., Sakata Y., Jakab E., Matsui T., Uddin Md. A.: J. Anal. Appl. Pyrolysis 2004, 72, 27.

[30] Wikström E.: “The role of Chlorine during Waste Combustion”, Praca doktorska, Department of Chemistry, Environmental Chemistry Umeĺ University, SE-901 Umeĺ, Sweden 1999.

[31] Buser H. R.: Chemosphere 1979, 6, 415.

[32] Kaminsky W., Sinn H.: Nachr. Chem. Tech. Lab. 1990, 38, nr 3, 333.

[33] Sun R.-D., Irie H., Nishikawa T., Nakajima A., Watanabe T., Hashimoto K.: Polym. Degrad. Stab. 2003, 79, 253.

[34] Tanaka M.: J. Mater. Cycles Waste Manag. 1999, 1, 10.

[35] Demirbas A.: J. Anal. Appl. Pyrolysis 2004, 72, 97.

[36] German K., Kulesza K., Florack M.: J. Mater. Cycles Waste Manag. 2006, 8, 116.

[37] Sobolewski A., Wasielewski R.: Chemik 2006, 4, 221.

[38] Fink J.: J. Anal. Appl. Pyrolysis 1999, 51, 239.

[39] Kulesza K., German K.: J. Anal. Appl. Pyrolysis 2003, 67, 123.

[40] German K.: J. Anal. Appl. Pyrolysis 2008, 82, 260.

[41] Zaby G.: Kunststoffe 2001, 91, nr 10, 238.

[42] Furukawa J., Saegusa T.: “Polymerization of aldehydes and oxides”, transl. into russ. Izd. “Mir”, Moskwa 1965, str. 65, 77.

[43] Miyoshi K., Alfafara C. G., Matsumura M.: J. Elektroanal. Chem. 2004, 568, 293.

[44] Weissermel K.: Arpe H. J.: „Industrielle Organische Chemie“, 5th edition, Wiley-VCH, Weinhaim 1998.

[45] Barański A., Rutkowski K., Cholewka E.: Chemik 1990, 1, 3.

[46] Lunin V. V., Lokteva E. S.: Iz. Akad. Nauk. Serija Chim. 1996, 7, 1609.

[47] Tavoularis G., Keane M. A.: J. Mol. Catal. A. Chem. 1999, 142, 187.

[48] Frimmel J., Zdrazil M.: J. Chem. Technol. Biotechnol. 1995, 63, 17.

[49] Wu W., Xu J., Ohnishi R.: Appl. Catal. B 2005, 60, 129.

[50] Courtemanche B., Levendis Y. A.: Environ. Eng. Sci. 1998, 15, nr 2, 123.

[51] Shemwell B., Levendis Y. A., Simons G. A.: Chemosphere 2001, 42, 785.

[52] Stull D. R., Prophet H.: JANAF thermochemical tables, 1971, Chase M. W. Jr., NIST- JANAF, Thermochemical Tables, J. Phys. Chem. Ref. Data, Monograph 1998, 9.

[53] Papuga P.: Praca magisterska, Politechnika Krakowska, 2004.

[54] Zhou Q., Tang Ch., Wang Y.-Z., Zheng L.: Fuel 2004, 83, 1727.

[55] Matsui T., Okita T., Fujii Y., Hakata T., Imai T., Bhaskar Th., Sakata Y.: Appl. Catal. A 2004, 261, 135.

[56] Sakata Y., Bhaskar Th., Uddin Md. A., Muto A., Matsui T.: J. Mater. Cycles Waste Manag. 2003, 5, 113.

[57] Akimoto M., Ninomiya K., Takami S., Ishikawa M., Sato M., Washio K.: Ind. Eng. Chem. Res. 2004, 41, 5393.

Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0