Koagenty sieciowania nadtlenkowego uwodornionego elastomeru butadienowo-akrylonitrylowego

M. Przybyszewska; M. Zaborski; A. Masek

Published : 2022-08-18

Vol. 54 No. 11-12 (2009)

Coagents for peroxide curing of hydrogenated acrylonitrile-butadiene elastomer

M. Przybyszewska M. Zaborski A. Masek

Abstract

Peroxide curing of acrylonitrile-butadiene rubber (HNBR/DCP), assisted with monoallyl maleate (MM) or itaconic acid (KI) in the presence of neutralizing substances: metal alkoxides [EtONa, (EtO)2Mg, (i-PrO)3Al, (t-BuO)4Ti] and magnesium hydroxide (Table 1, 2), was carried out. The effects of types of coagent and neutralizing substance on the kinetics of elastomer blend vulcanization (Table 3), on curing yield and density (Table 4) as well as on tensile strength of vulcanizates (Table 5) were investigated. It was found that coagents' application shortens vulcanization time, increases the process yield and improves tensile strength of cured products due to increase in vulcanizate relaxation ability being the result of a formation of additional ionic crosslinking points in its structure (Fig. 1). The most effective systems assisting the peroxide curing were: MM/(EtO)2Mg and KI/EtONa+Mg(OH)2.

Keywords

uwodorniony kauczuk butadienowo-akrylonitrylowy ; sieciowanie nadtlenkowe ; koagenty ; jonowe węzły sieci ; kinetyka sieciowania ; właściwości hydrogenated acrylonitrile-butadiene rubber ; peroxide curing ; coagents ; ionic crosslinking points ; curing kinetics ; properties

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Przybyszewska, M., Zaborski, M., & Masek, A. (2022). Coagents for peroxide curing of hydrogenated acrylonitrile-butadiene elastomer. Polimery, 54(11-12), 814–819. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1262

References

Dluzneski P. R.: Rubber Chem. Technol. 2001, 74,451.

2. Dikland H. G., van der Does L., Bantjes A.: Rubber Chem. Technol. 1993, 66,196.

3. Costin R., Henning S. K.: Rubber World 2006, 233, 28.

4. Class J.: Rubber World 1999, 220,35.

5. Murgic Z. H.y Jelencic J., Murgic L.: Polym. Eng. Sci. 1998,38, 689.

6. Drake R. E., Holliday J. J., Costello M. S.: Rubber World 1995,213,22.

7. Oh S. J., Keonig J. L.: Rubber Chem. Technol. 1999, 72, 334. -

8. Dikland H. G., Ruardy T., van der Does L., Bantjes A.: Rubber Chem. Technol. 1993,66,693.

9. Costin R., Ekwall R., Nagel W.: Rubber World 1992, 204, 27.

10. Grima Alvarez M. M., Talma A. G., Datta R. N., Noordermeer J. W. M.: Rubber Chem. Technol. 2006, 79, 694.

11. De Risi F. R., Noordermeer J. W. M.: Rubber Chem. Technol. 2007,80,83.

12. Zaborski M.: "Aktywnosc napelniaczy w osrodku elastomerowym", Wydawnictwo Politechniki Lodz-kiej, Lodz 1994, str. 29-41.

13. Flory P. J., Rehner J.: J. Chem. Phys. 1943,11,52.

14. Przybyszewska M., Zaborski M.: Compos. Interfaces 2009,16,131.

15. Zaborski M., Pietrasik J.: Polimery 2002, 47, 643

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0