Conversion-Temperature-Transformation (CTT) cure diagram for EPY® epoxy system

M. Urbaniak; K. Grudziński

Published : 2022-08-26

Vol. 52 No. 4 (2007)

Conversion-Temperature-Transformation (CTT) cure diagram for EPY® epoxy system

M. Urbaniak K. Grudziński

Abstract

Thermal decomposition of the filled epoxy system EPY® (“Epidian 6” with triethylenetetramine), applied for the production of machine foundation chocks, was studied using thermogravimetry and differential thermal analysis (TG-DTA). The results obtained and the results previously reached by differential scanning calorimetry (DSC) and rotational viscometry as well as by empirical model of the dependence of glass transition temperature on conversion degree let determine the cure diagram conversion - temperature - transformation (CTT) for the system studied. The cure diagram obtained makes possible the general insight into thermo-mechanical behavior of EPY® system during its curing and this way can be the useful tool for the assessment of curing quality of the material, required especially in the use for foundation chocks in their various applications.

Keywords

układ epoksydowy ; rozkład termiczny ; sieciowanie ; żelowanie ; konwersja ; temperatura zeszklenia ; diagram CTT epoxy system ; thermal decomposition ; curing ; gelation ; conversion ; glass transition temperature ; CTT diagram

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Urbaniak, M., & Grudziński, K. (2022). Conversion-Temperature-Transformation (CTT) cure diagram for EPY® epoxy system. Polimery, 52(4), 255–258. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1414

References

Barral L., Cano J., López A. J., López J., Nogueira P., Ramírez C.: J. Appl. Polym. Sci. 1996, 61, 1553.

2. Simon S. L., Gillham J. K.: J. Appl. Polym. Sci. 1994, 53, 709.

3. Adabbo H. E., Williams R. J.: J. Appl. Polym. Sci. 1982, 27, 1327.

4. Pascault J.-P., Sautereau H., Verdu J., Williams R. J. J.: "Thermosetting Polymers", Marcel Dekker, New York 2002, pp. 119--145.

5. Bryant E., Chartoff R.: "Crosslink Density and the Glass Transition in Thermosetting Polymers" in http://www.udri.udayton.edu/rpdl/Paper_CROSDENS/paper, University of Dayton 1998.

6. Williams R. J. J.: "Curing of Thermosets" in "Developments in Plastics Technology" (Ed. Whelan A., Craft J. L.), Elsevier Applied Science, London 1985, vol. 2, pp. 339--379.

7. Gillham J. K., Benci J. A., Noshay A.: J. Appl. Polym. Sci. 1974, 18, 951.

8. Gillham J. K.: Polym. Eng. Sci. 1979, 19, 676.

9. Urbaniak M., Grudziński K.: Polimery 2007, 52, xx.

10. Urbaniak M.: "Badania procesu utwardzania i jego wpływu na właściwości mechaniczne tworzywa epoksydowego EPY stosowanego na podkładki fundamentowe maszyn", PhD thesis, Szczecin University of Technology, Department of Mechanics, Szczecin 2004.

11. Grudziński K., Jaroszewicz W.: "Seating of machines and devices on foundation chocks cast of EPY resin compound", ZAPOL, Szczecin 2004, pp. 19--32.

12. Urbaniak M., Grudziński K.: Polimery 2004, 49, 89.

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0