The properties of elastomers obtained with the use of carboxylated acrylonitrile-butadiene rubber and new crosslinking substances

M. Gaca; M. Zaborski

doi:10.14314/polimery.2016.031

Published : 2021-01-24

Vol. 61 No. 1 (2016)

The properties of elastomers obtained with the use of carboxylated acrylonitrile-butadiene rubber and new crosslinking substances

M. Gaca M. Zaborski

DOI: https://doi.org/10.14314/polimery.2016.031

Abstract

In this work, new crosslinking substances containing zinc, sodium, magnesium and aluminum ions for carboxylated acrylonitrile-butadiene rubber (XNBR) were investigated. The crosslinking density of the vulcanizates obtained was studied by equilibrium swelling in solvents. Additionally, the results confirmed the presence of ionic clusters in metal-containing XNBR vulcanizates. It was proved that these crosslinks were generated due to interactions occurring between metal ions and functional groups of rubber, namely carboxyl groups. The appearance of these unconventional crosslinks was certified by various investigations, i.e. dynamic mechanical thermal analysis (DMTA), infrared studies or equilibrium swelling of vulcanizates in toluene under ammonia treatment.

Keywords

carboxylated acrylonitrile-butadiene rubber ; metal-containing compounds ; crosslinking ; ionic clusters karboksylowany kauczuk akrylonitrylowo-butadienowy ; związki zawierające metale ; sieciowanie ; klastry jonowe

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Gaca, M., & Zaborski, M. (2021). The properties of elastomers obtained with the use of carboxylated acrylonitrile-butadiene rubber and new crosslinking substances. Polimery, 61(1), 31–38. https://doi.org/10.14314/polimery.2016.031

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M. Gaca magdalena.gaca@p.lodz.pl

Affiliation
Technical University of Lodz, Institute of Polymer and Dye Technology, ul. Stefanowskiego 12/16, 90-924 Łódź, Poland

M. Zaborski

Affiliation
Technical University of Lodz, Institute of Polymer and Dye Technology, ul. Stefanowskiego 12/16, 90-924 Łódź, Poland