Polysiloxanes as supports for transition metal catalysts

M. Cypryk; P. Pospiech

doi:10.14314/polimery.2016.407

Published : 2021-01-24

Vol. 61 No. 6 (2016)

Polysiloxanes as supports for transition metal catalysts

M. Cypryk P. Pospiech

DOI: https://doi.org/10.14314/polimery.2016.407

Abstract

This article reviews the potential applicability of polysiloxanes as supports for transition metal catalysts. Unique physicochemical properties of polysiloxanes suggest their usefulness as catalyst supports. Polysiloxanes of various macromolecular topologies – linear and star-shaped and hyperbranched – with the functional side groups capable of binding transition metals were prepared. These polymers were used as carriers for palladium and rhodium complexes. The activities of so-immobilized complexes of transition metals in model reactions were comparable to that of the corresponding homogeneous complexes of these metals.

Keywords

polysiloxanes ; polymer-supported catalysts ; palladium ; rhodium ; immobilized catalysts polisiloksany ; polimerowe nośniki katalizatorów ; pallad ; rod ; katalizatory immobilizowane

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Cypryk, M., & Pospiech, P. (2021). Polysiloxanes as supports for transition metal catalysts. Polimery, 61(6), 407–412. https://doi.org/10.14314/polimery.2016.407

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M. Cypryk mcypryk@cbmm.lodz.pl

Affiliation
Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Łódź, Sienkiewicza 112, Poland

P. Pospiech

Affiliation
Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Łódź, Sienkiewicza 112, Poland