New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol

E. Kania; J. Lubczak

doi:10.14314/polimery.2014.851

Published : 2014-12-30

Vol. 59 No. 11-12 (2014)

New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol

E. Kania J. Lubczak

DOI: https://doi.org/10.14314/polimery.2014.851

Abstract

Barbituric acid (BA) cannot be used for synthesis of oligoetherols in a straightforward reaction with ethylene oxide (EO) or propylene oxide (PO) or alkylene carbonates because it undergoes tautomeric conversion into the tri-enolic form. The latter is insoluble in oxiranes and alkylene carbonates and does not react with them further. This obstacle was eliminated by initial functionalization of BA with glycidol (GL) leading to hydroxyalkyl derivatives of BA. The hydroxyalkyl derivatives of BA dissolve easily in oxiranes or in alkylene carbonates like ethylene (EC) or propylene (PC) carbonates and react with them to give oligoetherols with enhanced thermal stability.

Keywords

barbituric acid ; glycidol ; oligoetherols ; structure ; properties kwas barbiturowy ; glicydol ; oligoeterole ; struktura ; właściwości

Similar Articles

M. Bendyk, B. Jędrzejewska, J. Pączkowski, L. A. Linden, Hexaarylbisimidazoles and ketocyanine dyes as effective lectron transfer photoinitiating systems , Polimery: Vol. 47 No. 9 (2002)
D. Paukszta, S. Borysiak, Influence of reprocessing on the crystallization of polypropylene in PP/PA-6 blends , Polimery: Vol. 54 No. 2 (2009)
B. Osowiecka, J. Zieliński, J. Polaczek, Z. Machowska, Application of waste polycarbonate-furfurol thermolyzates to modification of petroleum bitumens , Polimery: Vol. 47 No. 4 (2002)
P. Redmer, B. Jędrzejewska, M. Pietrzak, J. Pączkowski, L. A. Linden, B. Pączkowska, Photochemical preparation of polymer-clay composites , Polimery: Vol. 47 No. 2 (2002)
M. Łapkowski, S. Golba, J. Żak, A. Stolarczyk, J. Sołoducho, J. Doskocz, W. W. Sułkowski, M. Bartoszek, Conductive polymers containing phenothiazine units in the main chains , Polimery: Vol. 54 No. 4 (2009)
Z. Czech, A. Butwin, B. Hefczyc, J. Zawadiak, Radical initiators and their influence on the viscosity and molecular weight of acrylic polymers applied in pressure-sensitive adhesives , Polimery: Vol. 54 No. 4 (2009)
M. Nowakowska, Olefin polymerization catalysts , Polimery: Vol. 47 No. 3 (2002)
W. M. Rzymski, H. J. Radusch, Thermoplastic elastomers manufactured of polymer blends , Polimery: Vol. 47 No. 4 (2002)
I. Kaya, S. Çulhaoglu, Syntheses, structures and properties of novel oligo(azomethine ether)s containing or not chlorine atoms in the main chain , Polimery: Vol. 54 No. 4 (2009)
W. M. Rzymski, Natural rubber and selected products of its chemical modification — historical outline , Polimery: Vol. 47 No. 5 (2002)

<< < 96 97 98 99 100 101 102 103 104 105 > >>

You may also start an advanced similarity search for this article.

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Kania, E., & Lubczak, J. (2014). New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol. Polimery, 59(11-12), 851–854. https://doi.org/10.14314/polimery.2014.851

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

E. Kania jml@prz.edu.pl

Affiliation
Rzeszów University of Technology, Department of Organic Chemistry; Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

J. Lubczak

Affiliation
Rzeszów University of Technology, Department of Organic Chemistry; Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland