New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol

E. Kania; J. Lubczak

doi:10.14314/polimery.2014.851

Published : 2014-12-30

Vol. 59 No. 11-12 (2014)

New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol

E. Kania J. Lubczak

DOI: https://doi.org/10.14314/polimery.2014.851

Abstract

Barbituric acid (BA) cannot be used for synthesis of oligoetherols in a straightforward reaction with ethylene oxide (EO) or propylene oxide (PO) or alkylene carbonates because it undergoes tautomeric conversion into the tri-enolic form. The latter is insoluble in oxiranes and alkylene carbonates and does not react with them further. This obstacle was eliminated by initial functionalization of BA with glycidol (GL) leading to hydroxyalkyl derivatives of BA. The hydroxyalkyl derivatives of BA dissolve easily in oxiranes or in alkylene carbonates like ethylene (EC) or propylene (PC) carbonates and react with them to give oligoetherols with enhanced thermal stability.

Keywords

barbituric acid ; glycidol ; oligoetherols ; structure ; properties kwas barbiturowy ; glicydol ; oligoeterole ; struktura ; właściwości

Similar Articles

A. Gałęski, E. Piórkowska, M. Pluta, Z. Kuliński, R. Masirek, Modification of physical properties of polylactide , Polimery: Vol. 50 No. 7-8 (2005)
A. Plichta, Z. Florjańczyk, G. Rokicki, Cyclic carbonates in the synthesis of biodegradable polymers , Polimery: Vol. 50 No. 7-8 (2005)
K. Sztuka, I. Kołodziejska, Edible films and surface coatings made of natural polymers for food packaging. Part 2, Modifications , Polimery: Vol. 53 No. 10 (2008)
E. Bortel, E. Witek, A. Kochanowski, M. Pazdro, Polyvinylamine - a base for new routes in hydrophilic polymers development , Polimery: Vol. 50 No. 7-8 (2005)
P. Radziszewski, Effect of the part of binders modified with SBS elastomer on frost resistance of aged mineral-asphalt blends , Polimery: Vol. 53 No. 10 (2008)
S. Kuciel, A. Liber, Assessment of efficiency of polyethylene reinforcement by filling with wood flour , Polimery: Vol. 50 No. 6 (2005)
J. Siejka-Kulczyk, M. Lewandowska, K. J. Kurzydłowski, Evaluation of degradation degree of dental ceramic/polymer composites for permanent fillings , Polimery: Vol. 51 No. 10 (2006)
D. Bieliński, P. Głąb, J. Chruściel, Modification of styrene-butadiene rubber with polymethylsiloxanes , Polimery: Vol. 52 No. 3 (2007)
R. N. Darie, C. Vasile, M. Kozłowski, The effect of compatibilization in reactive processing low density polyethylene/polyamide 6/EPDM blends , Polimery: Vol. 51 No. 9 (2006)
M. Żenkiewicz, The analysis of principal conditions of van Oss-Chaunhury-Good's method in investigations of surface layers of polymeric materials , Polimery: Vol. 51 No. 3 (2006)

<< < 107 108 109 110 111 112 113 114 115 116 > >>

You may also start an advanced similarity search for this article.

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Kania, E., & Lubczak, J. (2014). New method of synthesis of oligoetherols with pyrimidine ring from barbituric acid and glycidol. Polimery, 59(11-12), 851–854. https://doi.org/10.14314/polimery.2014.851

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

E. Kania jml@prz.edu.pl

Affiliation
Rzeszów University of Technology, Department of Organic Chemistry; Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

J. Lubczak

Affiliation
Rzeszów University of Technology, Department of Organic Chemistry; Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland