Nieizotermiczna krystalizacja ze stopu sulfonowanego poli(tereftalanu etylenu)

B. Ostrowska-Gumkowska; J. Ostrowska-Czubenko

Published : 2010-09-30

Vol. 55 No. 9 (2010)

Non-isothermal crystallization from the melt of sulfonated poly(ethylene terephthalate)

B. Ostrowska-Gumkowska J. Ostrowska-Czubenko

Abstract

The influence of copolymerization on the basic parameters of the nonisothermal crystallization process from the melt (Figs. 1,4), and also on the melting behavior (Fig. 7) of anionically modified polyethylene terephthalate) (K-X/SPET, Table 1) containing 1.9 - 10.1 % mol sulfonate groups has been studied. The obtained samples were studied by differential scanning calorimetry. It was observed that the crystallization process (Figs. 2, 3, 5, 6) and melting (Fig. 7) are crucially dependent on the structure of the chemical chain of the copolyester and the cooling rate of the polymer melt. The kinetic parameters for the crystallization process were determined by the Khanna and Liu method while the activation energy for the process according to the Kissinger method. The influence of concentration of ionic groups and the association phenomenon of these groups on the crystallization process (Tables 2, 4-6) as well as the melting of the studied ionic polymers (Tables 3, 7) was discussed.

Keywords

jonomer poliestrowy ; krystalizacja nieizotermiczna ; topnienie ; DSC polyester ionomer ; non-isothermal crystallization ; melting ; DSC

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Ostrowska-Gumkowska, B., & Ostrowska-Czubenko, J. (2010). Non-isothermal crystallization from the melt of sulfonated poly(ethylene terephthalate). Polimery, 55(9), 660–667. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1052

References

Hu Y. S., Baer A. H.: J. Appl. Polym. Sci. 2005, 98, 1629.

2. Kint D. P. R., Rude E., Llores J., Munoz-Guerra S.: Polymer 2002, 43, 7529.

3. Lee S. W., Ree M., Park C. E., Jung Y. K., Park C.-S., Jin Y. S., Bae D. C.: Polymer 1999, 40, 7137.

4. Orler B, E,, Moore R. B.: Macromolecules 1994, 27, 4774.

5. Liu X., Li Ch., Xiao Y, Zhang D., Zeng W.: J. Appl. Polym. Sci. 2006, 102, 2493.

6. Chisholm B. J., Richards W. D., Banach T. E., Soloveichik S., Kelley J. F., Bradtke G. R., Dhawan S.: J. Appl. Polym. Sci. 2006, 100, 4762.

7. Ostrowska-Gumkowska B.: Eur. Polym. J. 1994, 30, 875.

8. Włochowicz A., Ślusarczyk Cz., Narębska A., Szymański G.: J. Macromol Sci. Phys. 1992, 31, 239.

9. Ostrowska-Gumkowska B., Ostrowska-Czubenko J.: J. Macromol. Sci. Phys. 2008, 47, 675.

10. Ostrowska-Gumkowska B., Ostrowska-Czubenko J.: Eur. Polym. ]. 1988, 24, 803.

11. Ostrowska-Czubenko J., Ostrowska-Gumkowska B.: Eur. Polym. J. 1988, 24, 65.

12. Ostrowska-Gumkowska B., Ostrowska-Czubenko J.: Poi. J. Appl. Chem. 2009, 53, 161.

13. Ostrowska J., Ostrowska-Gumkowska B., Rybińska D., Szymański G.: Acta Polym. 1985, 36, 691.

14. Suchocka-Gałaś K.: Eur. Polym. J. 1994, 30, 609.

15. Suchocka-Gałaś K.: Eur. Polym. J. 1989, 25, 1291.

16. Kanamoto T., Hatsuya L, Ohoi M., Tanaka K.: Makromol. Chem. 1975, 176, 3497.

17. „Handbook of Chemistry and Physics” (red. Lide D. R., Haynes W. M.), 90th Ed. (2009-2010), CRC Press, Boca Raton 2009.

18. Orler E. B., Calhoun B. H. C., Moore R. B.: Macromokcules 1996, 29, 5965.

19. Ślusarczyk Cz., Włochowicz A.: Polimery 1997, 42, 353.

20. Ślusarczyk Cz., Włochowicz A.: Polimery 1997, 42, 532.

21. Sajkiewicz P.: Prace IPPT PAN 2003, 3, 3.

22. Przygocki W., Włochowicz A.: „Uporządkowanie makrocząsteczek w polimerach i włóknach”, Wydawnictwa Naukowo-Techniczne, Warszawa 2006, rozdz. 6.

23. Di Lorenzo M. L., Silvestre C.: Prog. Polym. Sci. 1999, 24, 917.

24. Kowalska B.: Polimery 2007, 52, 87.

25. Eder G.: „Non-isothermal Polymer Crystallization w: „Encyclopedia of Materials: Science and Technology” (red. Buschow K. H. J., Cahn R. W, Flemings M. C., Ilschner B., Kramer E. J., Mahajan S., Veyssière R), Elsevier Ltd. 2001, str. 6213-6218.

26. Liu M., Zhao Q., Wang Y, Zhang Ch., Mo Z., Cao S.: Polymer 2003, 44, 2537.

27. Zhao C., Zhang P, Yi L., Xu R, Wang X., Yong J.: Polym. Test. 2008, 27, 412.

28. Frąszczak Z., Królikowski B.: Polimery 2009, 54, 132.

29. Paukszta D., Borysiak S.: Polimery 2009, 54, 126.

30. Ozawa T.: Polymer 1971, 12, 150.

31. Jeziorny A.: Polymer 1978, 19, 1142.

32. Nadkarni V. M., Bulakh N. N., Jog J. P: Adv. Polym. Technol. 1993, 12, 73.

33. Sajkiewicz R, Carpaneto L., Wasiak A.: Polymer 2001, 42, 5365.

34. Sajkiewicz P: Polimery 2001, 46, 764.

35. Jog J. R: Polym. Rev. 1995, 35, 531.

36. Khanna R: Polym. Eng. Sci. 1990, 30, 1615.

37. Liu T., Mo Z., Wang S., Zhang H.: Polym. Eng. Sci. 1997, 37, 568.

38. Acar I. A., Durmus A., Özgümüs S.: J. Appl. Polym. Sci. 2007, 106, 4180.

39. Kissinger H. E.: J. Res. Nat. Bur. Stand. 1956, 57, 217.

40. Yang G. Z., Chen X., Wang W., Wang M., Liu T., Li C. Z.: J. Polym. Sci. Polym. Phys. 2007, 45, 976.

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