Spectroscopic and thermal studies on acrylic acid copolymers in interaction with uranyl

E. C. Buruiana; M. Nechifor; T. Buruiana

Published : 2022-08-18

Vol. 54 No. 5 (2009)

Spectroscopic and thermal studies on acrylic acid copolymers in interaction with uranyl

E. C. Buruiana M. Nechifor T. Buruiana

Abstract

Two acid copolymers derived from acrylic acid and itaconic acid i.e., poly(AA-co-IA) (7:2 molar ratio) or from the same acids and a small amount of N-vinylpyrrolidone i.e., poly(AA-co-IA-co-NVP) (7:3:2 molar ratio) were prepared by standard free-radical polymerization in aqueous solutions to be further used in preparation of complexes with uranyl ions. FT-IR and 1H NMR spectroscopy, thermogravimetric and relative viscosity measurements were used to characterize the resulting copolymers (PA-B, PA-T). Their polycomplexes with uranyl acetate, in aqueous solution and solid state (PA-Baq, PA-Taq and PA-Bss, PA-Tss, respectively), were analyzed by pH measurements, luminescence spectroscopy, FT-IR spectroscopy and thermal analyses for the latter ones.

Keywords

kopolimery rozpuszczalne w wodzie ; polimeryzacja rodnikowa ; kation uranylowy ; kompleksy polimerowe ; luminescencja water-soluble copolymers ; radical polymerization ; uranyl cation ; polymer complexes ; luminescence

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Buruiana, E. C., Nechifor, M., & Buruiana, T. (2022). Spectroscopic and thermal studies on acrylic acid copolymers in interaction with uranyl. Polimery, 54(5), 354–360. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1209

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E. C. Buruiana emilbur@icmpp.ro

Affiliation
"Petru Poni" Institute of Macromolecular Chemistry, 41A Aleea Grigore Ghica Voda, lasi, RO-700487

M. Nechifor

T. Buruiana