Badanie właściwości inkluzyjnych p-tert-butylokaliksarenów metodą inwersyjnej chromatografii gazowej

M. Białoń; J. Hetper

Published : 2022-08-26

Vol. 52 No. 4 (2007)

Investigation of inclusion properties of p-tert-butylcalixarenes by inversion gas chromatography method

M. Białoń J. Hetper

Abstract

Inclusion properties of p-tert-butylcalixarenes having 4, 6 or 8 mers in a cycle [formula (I), Fig. 3] and of their acetates were characterized using inverse gas chromatography. Two homologous series of solutes were used in the study - aliphatic alcohols and benzene and its homologues. It was found that inclusion properties significantly depend on the size of molecular gap of cyclomer (Fig. 1, 2, 4 and 5). Change of hydroxyl groups of calixarene to acetate ones does not influence essentially the possibility of formation of „host-guest” complexes. The results obtained by QSRR method, were confirmed with Kováts indices determined (Table 3).

Keywords

kaliksareny ; inwersyjna chromatografia gazowa ; kompleksy inkluzyjne calixarenes ; inverse gas chromatography ; inclusion complexes

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Białoń, M., & Hetper, J. (2022). Investigation of inclusion properties of p-tert-butylcalixarenes by inversion gas chromatography method. Polimery, 52(4), 274–279. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1417

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