Progress in controlled/living polymerization in aqueous media. Part I. Principles and methods

J. Qiu; B. Charleux; K. Matyjaszewski

Published : 2022-09-19

Vol. 46 No. 7-8 (2001)

Progress in controlled/living polymerization in aqueous media. Part I. Principles and methods

J. Qiu B. Charleux K. Matyjaszewski

Abstract

A review with 113 references covering fundamentals, principal phenomena, general features and experimental criteria for CLP, viz., (i) fullfilment of the first-order reaction kinetics (i.e., ln(monomer concentration), or ln([M]0/[M]), is a linear function of time; no termination; constant concentration of active centers); (ii) number-average M is a linear function of the degree of monomer conversion; (Hi) narrow MWD; (iv) long lifetime of polymer chains able to propagate (owing to absence of chain transfer and termination). CLP methods are presented, viz., anionie polymerization including group transfer polymerization (GTP), cationic polymerization, which is much more difficult to carry out; ring opening metathesis polymerization; coordination polymerization; radical polymerization (involving stable free radicals (SFRP); atom transfer (ATRP); and utilizing the degenerative chain transfer reaction with chain transfer agent used in excess over radical initiator).

Keywords

kontrolowana polimeryzacja żyjąca ; żyjąca polimeryzacja anionowa ; polimeryzacja z przeniesieniem grupy ; żyjąca polimeryzacja kationowa ; żyjąca polimeryzacja typu metatezy z otwarciem pierścienia ; żyjąca polimeryzacja koordynacyjna controlled/living polymerization ; living anionie polymerization ; group-transfer polymerization (GTP) ; living cationic polymerization ; living ring-opening metathesis polymerization (ROMP) ; living coordination polymerization ; living radical polymerization

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Qiu, J., Charleux, B., & Matyjaszewski, K. (2022). Progress in controlled/living polymerization in aqueous media. Part I. Principles and methods. Polimery, 46(7-8), 453–460. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/2094

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J. Qiu polimery@ichp.pl

Affiliation
Center of Macromolecular Engineering, Department of Chemistry, Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, USA

B. Charleux

K. Matyjaszewski