Microwave assisted synthesis of unsaturated polyester resins

J. Pielichowski; P. Penczek; D. Bogdal; E. Wolff; J. Gorczyk

Published : 2022-09-01

Vol. 49 No. 11-12 (2004)

Microwave assisted synthesis of unsaturated polyester resins

J. Pielichowski P. Penczek D. Bogdal E. Wolff J. Gorczyk

Abstract

A novel method of synthesis of unsaturated polyester (UP) resins, based on the catalytic (i.e., with lithium chloride) copolymerization of alkylene oxides (i.e., epichlorohydrin) with acid anhydrides (i.e., maleic, phthalic ones) under microwave irradiation is described. In comparison with condensations of acid anhydrides with diols, this reaction proceeds without emission of any volatile product. All the syntheses were performed under both either conventional heating or microwave irradiation (two variants: mono- and multimode). In general, the application of microwave irradiation allows to reduce the reaction time.

Keywords

promieniowanie mikrofalowe ; nienasycone żywice poliestrowe ; żywice poliestrowe ; bezwodniki kwasowe ; epichlorohydryna ; czas reakcji microwave irradiation ; unsaturated polyesters resins ; acid anhydrides ; epichlorohydrin ; reaction time

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Pielichowski, J., Penczek, P., Bogdal, D., Wolff, E., & Gorczyk, J. (2022). Microwave assisted synthesis of unsaturated polyester resins. Polimery, 49(11-12), 763–766. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1809

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J. Pielichowski polimery@ichp.pl

Affiliation
Cracow University of Technology, Department of Polymer Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków

P. Penczek

Affiliation
Cracow University of Technology, Department of Polymer Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków

D. Bogdal

Affiliation
Cracow University of Technology, Department of Polymer Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków

E. Wolff

Affiliation
Cracow University of Technology, Department of Polymer Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków

J. Gorczyk

Affiliation
Cracow University of Technology Department of Polymer Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków