Polistyren o ograniczonej palności otrzymywany metodą polimeryzacji suspensyjnej w obecności bezhalogenowych dodatków

P. Jankowski; M. Kędzierski

Published : 2011-01-30

Vol. 56 No. 1 (2011)

Synthesis of polystyrene of reduced flammability by suspension polymerization in the presence of halogen-free additives

P. Jankowski M. Kędzierski

Abstract

A method for the synthesis of polystyrene of reduced flammability by suspension polymerization in the presence of organic phosphor compounds or their compositions with organically modified layered aluminosilicates of the montmorillonite type has been developed. The additives or their compositions were introduced into the polystyrene during suspension polymerization by applying such procedures as to minimize their effects on the process. Polystyrenes of reduced flammability up to maximal vertical and horizontal burning rate categories of V-1 and FH-1, respectively, and of an oxygen index in the 21-26 % range were obtained.

Keywords

polimeryzacja suspensyjna ; polistyren o ograniczonej palności ; bezhalogenowe antypireny ; związki fosforowe ; montmorylonit ; modyfikacja suspension polymerization ; polystyrene of reduced flammability ; halogen-free additives ; phosphor compounds ; montmorillonite ; modification

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Jankowski, P., & Kędzierski, M. (2011). Synthesis of polystyrene of reduced flammability by suspension polymerization in the presence of halogen-free additives. Polimery, 56(1), 20–26. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/887

References

Pat. USA 4 359 538 (1982).

2. Pat. USA 4 699 943 (1987).

3. Pat. USA 5 302 625 (1994).

4. Pat. USA 6 27 272 (2001).

5. Grause G., Ishibashi J., Kameda T., Bhaskar T., Yoshioka T.: Polym. Degmd. Stab. 2010, 95, 1129.

6. Mitan N. M. M., Brebu M, Bhaskar T., Muto A., Sakata Y: J. Mater. Cycles Waste Manag. 2007, 9, 56.

7. Garbarski J., Fabijański M.: ,”Modyfikacja Polimerów”, Kudowa, wrzesień 2005, mat. konf., str. 187.

8. Hamm S., Strikkeling M., Ranken P. R, Rothenbacher K. P.: Chemosphere 2001, 44, 1353.

9. Lu H., Wilkie C. A.: Polym. Degrad. Stab. 2010, 95, 564.

10. Brebu M., Jakab E., Sakata Y.: J. Anal. Appl. Pyrolysis 2007, 79, 346.

11. Ebdon J. R., Hunt B. J., Joseph P.: Polym. Degrad. Stab. 2004, 83, 181.

12. Uhl F. M., Wilkie C. A.: Polym. Degrad. Stab. 2002, 76, 111.

13. Zheng X., Wilkie C. A.: Polym. Degrad. Stab. 2003, 81, 539.

14. Wang Z., Du X., Yu H., Jiang Z., Liu J., Tang T.: Polymer 2009, 50, 5794.

15. Zhang J., Jiang D. D., Wang D., Wilkie C. A.: Polym. Degrad. Stab. 2006, 91, 2665.

16. Ding-Ru Yei, Shiao-Wei Kuo, Huei-Kuan Fu, Feng-Chin Chang: Polymer 2005, 46, 741.

17. Li H., Yu Y, Yang Y: Eur. Polym. J. 2005, 41, 2016.

18. Ding C., Guo B., He H., Jia D., Hong H.: Eur. Polym. J. 2005, 41, 1781.

19. Price D., Cunliffe L. K., Bullett K. J.: Polym. Degrad. Stab. 2007, 92, 1101.

20. Canadell J., Hunt B. J., Cook A. G., Mantecon A., Cadiz V.: Polym. Degrad. Stab. 2007, 92, 1482.

21. Kicko-Walczak E., Jankowski P., Legocka L: Przem. Chem. 2007, 86, 203.

22. Muraki T., Ueta M., Ihara E., Inoue K.: Polym. Degrad. Stab. 2004, 84, 87.

23. Chigwada G., Wilkie C. A.: Polym. Degrad. Stab. 2003, 80, 551.

24. Nyambo C., Kandare E., Wang D., Wilkie C. A.: Polym. Degrad. Stab. 2008, 93, 1656.

25. Hertz Z., Krajewski B., Penczek I., Płochocki A., Wiecheć T.: „Polistyren”, WNT, Warszawa 1962.

26. Fu X., Qutubuddin S.: Polymer 2001, 42, 807.

27. Hiatt R., Smythe R. J., Me Coleman C.: Can. J. Chem. 1971, 49, 1708.

28. Pol. zgl. pat. P-386868 (2008).

Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0