The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites

Maciej Mrówka; Małgorzata Szymiczek; Tomasz Machoczek; Joanna Lenża; Jakub Matusik; Piotr Sakiewicz; Magdalena Skonieczna

doi:10.14314/polimery.2020.11.5

Published : 2020-12-17

Vol. 65 No. 11-12 (2020)

The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites

Maciej Mrówka Małgorzata Szymiczek Tomasz Machoczek Joanna Lenża Jakub Matusik Piotr Sakiewicz Magdalena Skonieczna

DOI: https://doi.org/10.14314/polimery.2020.11.5

Abstract

The impact of the addition of the nanofiller – halloysite – on the mechanical, physicochemical and biological properties of a nanocomposite, in which thermoplastic polyurethane fulfilled the role of the matrix was investigated. The nanocomposite was obtained by extrusion in three variants with 1, 2 and 3 wt % halloysite. The nanostructure of the obtained materials was confirmed using Atomic Force Microscopy (AFM). Based on the mechanical tests carried out, it was proven that the obtained nanocomposites were characterized by a tensile modulus greater than the polyurethane constituting the matrix. The density and hardness of the nanocomposites had changed within error limits compared to unmodified polyurethane. Biological tests showed no cytotoxicity of all the tested materials to normal human dermal fibroblasts (NHDF). Degradation tests were carried out in artificial plasma and showed that samples with 2 wt % halloysite addition had the best ratio of tensile strength and elongation at break to elasticity modulus.

Keywords

nanocomposites ; thermoplastic polyurethanes ; halloysite ; mechanical properties ; cytotoxicity ; tests ; degradation nanokompozyty ; termoplastyczne poliuretany ; haloizyt ; właściwości mechaniczne ; badania cytotoksyczne ; degradacja

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Mrówka, M., Szymiczek, M., Machoczek, T., Lenża, J., Matusik, J., Sakiewicz, P., & Skonieczna, M. (2020). The influence of halloysite on the physicochemical, mechanical and biological properties of polyurethane- -based nanocomposites. Polimery, 65(11-12), 784–791. https://doi.org/10.14314/polimery.2020.11.5

References

Mrówka M., Szymiczek M., Lenża J.: Journal of Achievements in Materials and Manufacturing Engineering 2019, 95, 13. http://dx.doi.org/10.5604/01.3001.0013.7620

[2] Larson E.: “Thermoplastic Material Selection 1st Edition A Practical Guide”, Elsevier BV, Amsterdam 2015.

[3] Brzeska J., Dacko P., Janeczek H. et al.: Polimery 2010, 55, 41. http://dx.doi.org/10.14314/polimery.2010.041

[4] Cheremisinoff N.P.: “Materials Selection Deskbook 1st Edition”, Elsevier BV, Amsterdam 1996.

[5] Turi E.: “Thermal Characterization of Polymeric Materials”, Elsevier BV, Amsterdam 1981.

[6] Olędzka E., Sobczak M., Kołodziejski W.L.: Polimery 2007, 52, 795. http://dx.doi.org/10.14314/polimery.2007.795

[7] Krzyżak A., Kosicka E., Szczepaniak R., Szczepaniak T.: Journal of Achievements in Materials and Manufacturing Engineering 2019, 95, 5. http://dx.doi.org/10.5604/01.3001.0013.7619

[8] Brydson J.A.: “Plastics Materials 5th Edition”, Elsevier, eBook ISBN: 9781483144795.

[9] Spirkova M., Pavlicevic J., Strachota A. et al.: European Polymer Journal 2011, 47, 959. https://doi.org/10.1016/j.eurpolymj.2011.01.001

[10] Cooper S.L., Guan J.: “Advances in Polyurethane Biomaterials”, Elsevier BV, Amsterdam 2016.

[11] Woźniak P., Bil M., Ryszkowska J. et al.: Acta Biomaterialia 2010, 6 (7), 2484. http://dx.doi.org/10.1016/j.actbio.2009.10.022

[12] „Biomateriały tom 4” (Eds. Błażewicz S., Marciniak J.), Wydawnictwo EXIT, 2017.

[13] Twaiq F., Chang K.X., Ling J.Y.W.: IOP Conference Series: Materials Science and Engineering 2017, 206, 012066.

[14] Fizir M., Dramou P., Dahiru N.S. et al.: Microchimica Acta 2018, 185, 389. https://doi.org/10.1007/s00604-018-2908-1

[15] Rozhina E., Ishmuhametov I., Batasheva S. et al.: BioNanoScience 2018, 8, 310. http://dx.doi.org/10.1007/s12668-017-0453-8

[16] Matusik J.: “Natural and synthetic layered minerals in nanotechnology”, Wydawnictwo AGH, Kraków, 2017.

[17] Sulong A.B., Gaaz T.S., Sahari J.: Procedia-Social and Behavioral Sciences 2015, 195, 2748. https://doi.org/10.1016/j.sbspro.2015.06.386

[18] Gaaz T.S., Sulong A.B., Ansari M.N.M. et al.: Materials Technology Advanced Performance Materials 2016, 32, 430. https://doi.org/10.1080/10667857.2016.1265278

[19] Gaaz T.S., Luaibi H.M., Al.-Amiery A.A. et al.: Results in Physics 2018, 9, 33. https://doi.org/10.1016/j.rinp.2018.02.008

[20] Martini J., Pollet E., Averous L. et al.: Polymer 2014, 55, 5226. https://doi.org/10.1016/j.polymer.2014.08.049

[21] Sołtys J., Schomburg J., Sakiewicz P. et al.: „Sorbenty mineralne. Surowce, energetyka, ochrona środowiska, nowoczesne technologie”, Wydaw. AGH, 2013, pp. 457—469.

[22] Wierzbicka E., Legocka I., Wardzińska-Jarmulska E. et al.: Polimery 2016, 61, 670. http://dx.doi.org/10.14314/polimery.2016.670

[23] Szczepanik B., Słomkiewicz P., Garnuszek M. et al.: Journal of Molecular Structure 2015, 1084, 16. https://doi.org/10.1016/j.molstruc.2014.12.008

[24] Bardon C., Bieber M.T, Cuiec L., et al.: Revue de l’ Institut Francais du Pétrole 2006, 38, 621. https://doi.org/10.2516/ogst:1983037

[25] Derkowski A., Bristow T.F.: Clays and Clay Minerals 2012, 60, 348. http://dx.doi.org/10.1346/CCMN.2012.0600402

[26] Orsini L., Remy J.C.: Science du sol 1976, 4, 269.

[27] Środoń J.: Clay Minerals 2009, 44, 421. https://doi.org/10.1180/claymin.2009.044.4.421

[28] Kumar A.P., Depan D., Singh Tomer N. et al.: Progress in Polymer Science 2009, 34, 479. https://doi.org/10.1016/j.progpolymsci.2009.01.002

[29] https://www.campusplastics.com/campus/en/datasheet/Elastollan® 1185 A/BASF Polyurethanes GmbH/59/65a16011 (available May 17, 2020).

[30] Troadec M.B., Glaise D., Lamirault G. et al.: Genomics 2006, 87, 93. https://doi.org/10.1016/j.ygeno.2005.08.016

[31] Mrowka M., Machoczek T., Jureczko P. et al.: Polish Journal of Chemical Technology 2019, 1, 1. https://dx.doi./10.2478/pjct-2019-0001

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Maciej Mrówka maciej.mrowka@polsl.pl

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Małgorzata Szymiczek

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Tomasz Machoczek

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Theoretical and Applied Mechanics, Konarskiego 18A, 44–100 Gliwice, Poland

Joanna Lenża

Affiliation
Krahn Chemie Polska Sp. z o.o., Marcelińska 90, 60–324 Poznań, Poland

Jakub Matusik

Affiliation
AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Krakow, Poland.

Piotr Sakiewicz

Affiliation
Silesian University of Technology, Faculty of Mechanical Engineering, Department of Engineering Materials and Biomaterials, Konarskiego 18A, 44–100 Gliwice, Poland

Magdalena Skonieczna

Affiliation
Silesian University of Technology, Biotechnology Centre, Krzywoustego 8, 44–100 Gliwice, Poland.