Studies on ethoxylated phenolic resins. Part. I. Surface characteristics and properties of coatings on metal

A.S. Mohamed; M.Z. Mohamed; E.M. Sadek; A.M. Motawie

Published : 2022-09-01

Vol. 49 No. 6 (2004)

Studies on ethoxylated phenolic resins. Part. I. Surface characteristics and properties of coatings on metal

A.S. Mohamed M.Z. Mohamed E.M. Sadek A.M. Motawie

Abstract

Phenolic resins such as resol or novolac phenol-formaldehyde (PF) ones have been synthesized and etherified with poly(ethylene glycol) (PEG) with different molecular weights (1000, 1500, 4000). The solution behaviors in aqueous medium of the prepared resol and novolac phenol-formaldehyde ethoxylated resins, as nonionic polymeric surfactants with different hydrophilic chains lengths, have been interpreted. Surface and interfacial tension measurements as well as emulsifying power and foaming properties of the tested nonionic polymeric surfactants were studied. The critical micelle concentration (CMC) and the value of free surface energy reached at this concentration gamma(CMC) were also measured. Coatings on metal, made of the investigated phenolic ethoxylated resins, were prepared and evaluated as varnishes. This study indicated that the free surface energy of the prepared nonionic polymeric surfactants as well as the ease of formation of aggregates increase with PEG hydrophilic chain length increasing. Also, it was found that coating compositions based on resol PF ethoxylated resins with PEG-4000 offer chain flexibility and excellent coating properties.

Keywords

żywica fenolowo-formaldehydowa ; żywica rezolowa ; żywica nowolakowa ; oksyetylenowanie ; związki powierzchniowo czynne ; związki polimerowe niejonowe ; właściwości powierzchniowe ; powłoki na podłożu metalicznym ; właściwości mechaniczne resol or novolac phenol-formaldehyde resins ; ethoxylation ; nonionic polymeric surfactants ; surface properties ; coatings on metals ; mechanical properties

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Mohamed, A., Mohamed, M., Sadek, E., & Motawie, A. (2022). Studies on ethoxylated phenolic resins. Part. I. Surface characteristics and properties of coatings on metal. Polimery, 49(6), 398–403. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1765

References

Mather R. R: Colloids Surf. 1989, 37, 131

2. Muroi S . Shokubai 1983, 56,36

3. Grant R, L: Paper Technol. 1962, 3, 339.

4. Kuo P. L,, Chang T. C., Lu L, M.: J. Appl. Polym, Sci 1992, 44, 859,

5. Dixon J. K., Lamer V. K., Li C., Messinger S,, Linford H. B.: J. Colloid Interface Sci, 1967, 23,465.

6. Walles W. E.: J. Colloid Interface Sci. 1968, 27, 797.

7. Anthony A. J,, King P. H., Randall FW. J. Appl. Polym. Sci, 1975, 19, 37.

8. Clark A. Q,, Herrington T. M., Petzold J. C.: Colloids Surf. 1990, 44, 247.

9. Kuo PL, Chen C.J. Polym, Sci, Part A: Polym. Chem, 1993, 31, 99,

10. Kobayashi S,, Suh K. D., Shirokua ¥.: Macromolecules 1989, 22, 2363.

11. Kuo P, L,, Cheng V,, Chen C, L.: J. Appl. Polym. Sci 1999, 71, 805,

12. Turto N, J., Arora K.S.: Polymer 1986, 27, 783.

13. Chu D. ¥,, Thomas J. R: Macromolecules 1989, 17, 2132.

14. Price C.: Pure Appl. Chem. 1983, 55, 1563.

15. Kuo P. L., Hung M. Nu: J. Appt, Polym. Sci. 1993, 1571. 16,

16. Rosen M. Ju: “Surfactants and Interfacial Phenomena”, John Willey & Sons Inc., New York 1978,

17. Jonsson B., Lindman B,, Holmberg K., Kronberg B: “Surfactants and Polymers in Aqueous Solution John Willey & Sons Ltd,, New York 1998,

18. Zaki N., Al Sabagh A.: Tonside Surfactants, Detergents 1997, 34(1),12,

19. Edward G. J: “Proceedings of the IS and T-Annual Conference Soc. Imaging Sci. Technol”, Springfield, VA, USA 1996, p. 531.

20. Edans M. W,, Nace V. M,, Knoell J. C. Poly. Mat. Sci. Eng. 1993, 69, 551.

21. Braun D., Cherdron H., Ritter H.: “Polymer Synthesis: Theory and Practice Fundamentals, Methods, Experiments”, 3rd ed., Springer-Verlag, Berlin— Heidelberg—New York 2001

22. Liston T. J. Am. Chem, Soc, 1938, 60, 1264. .

23. Ismail D. A., Negm N. A.J. Faculty Educ. Ain Shams Univ. 2001, No. 26.

24. Findlay A.: Practical Physical Chemistry”, 6th ed., Longmans Pub., 1963, p. 92.

25. Hampson J. W., Cornell D. Ga J. Am. Oil Chem, Soc. 1996, 73, 891 403

26. Chen K. M,, Wang H.R: J. Am. Oil Chem. Soc. 1992, 69. 27,

27. Eley D. D,, Hey M.J., Symonds J. D.: Colloids Surf. 1988, 32, 87. 28,

28. Ross J,, Milles G, D.: Oil Soap 1941, 18, 90.

29. Hikota T., Meguro K, J.: Japanese Chem, Soc. 1970, 47, 158.

30. EF-Sukkary M. M., El-Dip F., El-Sawy A. A. Hungarian J. Ind. Chem. 1986, 14, 223,

31. Fineman M. N., Brown G, L, Meyers R. J.: J. Phys. Chem, 1952, 56, 963,

32. West C. C,, Harwell J. H.: Environ. Sci. Technol. 1992, 26, 2324,

33. Magng B,, Iliopoulos I., Audebert R. in: “Macromolecular Complexes in Chemistry and Biology’ Springer-Verlag, Berlin 1994

34. Wang T. K,, lligpoutlos 1., Audebert R.: Polym. Bull 1988, 20, 577.

35. Wang T. K,,liopoulos1, Audebert R.: Am. Chem. Soc. 1989, 30(2),377.

36. Brydson J. A. “Plastic Materials” 3rd ed., Newnes-Butterworths, London 1975.

37. Feldman D., Barbalata A.: “Synthetic Polymers. Technology, Properties, Applications”, 1st ed., Chapman &Hall, London 1996,

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A.S. Mohamed polimery@ichp.pl

Affiliation
Egyptian Petroleum Research Institute, Petrochemical Department, Nasr City, Hai Al-Zehour 11727 Cairo, Egypt

M.Z. Mohamed

Affiliation
Egyptian Petroleum Research Institute, Petrochemical Department, Nasr City, Hai Al-Zehour 11727 Cairo, Egypt

E.M. Sadek

Affiliation
Egyptian Petroleum Research Institute, Petrochemical Department, Nasr City, Hai Al-Zehour 11727 Cairo, Egypt

A.M. Motawie

Affiliation
Egyptian Petroleum Research Institute, Petrochemical Department, Nasr City, Hai Al-Zehour 11727 Cairo, Egypt