Preparation and characterization of halogen-free flame retardant MCA core-shell microcapsules coated with melamine or acrylic acid resin

Xiaoyi Zhang; Zheng Gu; Jinyong Sui; Zhenxu Li Zhenxu Li; Lining Song; Lina Yang; Ning Wang; Jie Zhao

doi:10.14314/polimery.2021.4.4

Published : 2021-05-07

Vol. 66 No. 4 (2021)

Preparation and characterization of halogen-free flame retardant MCA core-shell microcapsules coated with melamine or acrylic acid resin

Xiaoyi Zhang https://orcid.org/0000-0003-4047-5046 Zheng Gu https://orcid.org/0000-0001-9521-2863 Jinyong Sui https://orcid.org/0000-0002-4232-3540 Zhenxu Li Zhenxu Li https://orcid.org/0000-0003-3998-9090 Lining Song https://orcid.org/0000-0002-5671-4745 Lina Yang https://orcid.org/0000-0002-5518-050X Ning Wang https://orcid.org/0000-0002-2509-3886 Jie Zhao https://orcid.org/0000-0002-6754-3785

DOI: https://doi.org/10.14314/polimery.2021.4.4

Abstract

The resin melamine cyanurate (MCA) core-shell microcapsules were prepared by surface coating
modification of halogen-free flame retardant MCA using melamine resin and acrylic resin as wall materials. The influence of different wall materials on the coating effect of halogen-free flame retardant MCA was studied by SEM, particle size analysis, IR, and DSC and TGA methods. The results showed that the melamine resin had a high degree of polymerization and decomposed at about 160°, which had a surface modification effect on MCA and did not affect its flame retardant performance. The surface coating rate of poly(methyl methacrylate) PMMA-MCA core-shell microcapsules was about 80%. After
adding acrylic acid (AA) as the second monomer the coating effect was significantly improved and the thermal decomposition temperature of the wall material of the microcapsule was reduced.

Keywords

melamine cyanurate ; resin ; microcapsule ; modified cyjanuran melaminy ; żywica ; mikrokapsułka ; modyfikacja

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Zhang, X., Gu, Z., Sui, J., Zhenxu Li, Z. L., Song, L., Yang, L., … Zhao, J. (2021). Preparation and characterization of halogen-free flame retardant MCA core-shell microcapsules coated with melamine or acrylic acid resin. Polimery, 66(4), 245–252. https://doi.org/10.14314/polimery.2021.4.4

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