New aromatic polyesteramides: synthesis and properties

I. Sava

Published : 2011-04-30

Vol. 56 No. 4 (2011)

New aromatic polyesteramides: synthesis and properties

I. Sava

Abstract

New aromatic polyesteramides with fairly high average molecular weight [(72-229) · 10³] and rather narrow polydispersity in the range of 2.0-3.7 were prepared by polycondensation reaction of different aromatic diamines with a diacid chloride containing preformed ester groups. These polymers, easily soluble in N-methylpyrrolidinone, were cast into transparent, flexible films of various thickness (5-40 μm). The polymers showed high thermal stability with initial decomposition temperature above 340 °C and glass transition temperature in the range of 190-220 °C. The viscoelastic behavior of the new polyesteramides was investigated in the temperature range from -100 °C to 260 °C by dynamic mechanical analysis.

Keywords

poliestroamidy ; synteza ; budowa chemiczna ; odporność cieplna ; właściwości lepkosprężyste polyesteramides ; synthesis ; chemical structure ; thermal stability ; viscoelastic properties

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Sava, I. (2011). New aromatic polyesteramides: synthesis and properties. Polimery, 56(4), 263–270. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/915

References

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17. Sava I., Ronova I., Bruma M.: Polym. ]. 2006, 38, 940.

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22. Gonzales J. M., Munoz M. E., Cortazar M., Santamaria A., Pena J. J.: J. Polym. Sci Part B Polym. Phys. 1990, 28, 1533.

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25. Cristea M., Gaina C., Gheorghiu-Ionita D., Gaina V: J. Therm. Anal. Cal. 2008, 93, 69.

Remove 1. Preston J.: „Aromatic polyamides” in „Encyclopedia of Polymer Science and Engineering” (Eds. Mark H. R, Bikales N. M., Overberger C. G., Menges G.), Wiley, New York 1988, Vol. 11, pp. 381-409.

2. Hergenrother P. M.: High Perform. Polym. 2003, 15, 15.

3. Cassidy P. E., Aminabhavi T. M., Reddy V. S.: „Heat-resistant polymers” in „Kirk-Othmer Encyclopedia of Chemical Technology” (Ed. Kroschwitz J. I.), Wiley, New York 1994, pp. 1045-1070.

4. Schulz B., Bruma M., Brehmer L.: Adv. Mater. 1997, 9, 601.

5. Sroog C. E.: Prog. Polym. Sci. 1991, 16, 561.

6. Bruma M., Sava I., Mercer F. W., Negulescu I., Daly W., Fitch J., Cassidy P.: High Perform. Polym. 1995, 7, 411.

7. Sava I., Iosip M. D., Bruma M., Hamciuc C., Robison J., Okrasa L., Pakula T.: Eur. Polym. J. 2003, 39, 725.

8. Schab-Balcerzak E.: Polimery 2008, 53, 663.

9. Guang Li, Caymans R. J.: Polymer 1997, 38, 4891.

10. Hsiao S. H., Leu W. T.: Polym. Int. 2005, 54, 392.

11. Vera M., Franco L., Puiggali J.: J. Polym. Sci. Part A Polym. Chem. 2008, 46, 661.

12. Atkins K. M., Lopez D., Knight D. K., Mequanint K., Gillies E. R.: J. Polym. Sci. Part A Polym. Chem. 2009, 47, 3757.

13. Bilibin A., Tenkovtsev A., Piraner O.: Vysokomol. Soedin. A 1984, 26, 2570.

14. Sava I., Hamciuc C., Bruma M., Hamciuc E.: Rev. Roum. Chim. 2001, 46, 1161.

15. Sava I., losip M. D., Bruma M.: Rev. Roum. Chim. 2004, 49, 515.

16. Sava I., Bruma M.: Rev. Roum. Chim. 2004, 49, 69.

17. Sava I., Ronova I., Bruma M.: Polym. ]. 2006, 38, 940.

18. Lu Q. H., Yin J., Xu H. J., Zhang J. M., Sun L. M., Zhu Z. K., Wang Z. G.: J. Appl. Polym. Sci. 1999, 72, 1299.

19. Mercer F. W, McKenzie M. T., Bruma M., Schulz B.: Polym. Int. 1994, 33, 399.

20. Saxena A., Prabhakaran P. V., Rao V. L., Ninan K. N.: Polym. M. 2005, 54, 544.

21. Hypercube Inc. (Ontario), 2002, Hyperchem Version 7.5.

22. Gonzales J. M., Munoz M. E., Cortazar M., Santamaria A., Pena J. J.: J. Polym. Sci Part B Polym. Phys. 1990, 28, 1533.

23. Hamciuc C., Hamciuc E., Ipate A. M., Okrasa L.: Polymer 2008, 49, 681.

24. Cristea M., Gheorghiu-Ionita D., Bruma M., Simionescu B. C.: J. Therm. Anal. Cal. 2008, 93, 63.

25. Cristea M., Gaina C., Gheorghiu-Ionita D., Gaina V: J. Therm. Anal. Cal. 2008, 93, 69.

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