Synthesis and properties of carboxy derivative of Epidian 6 monomethacrylate

M. Bratychak; O. Iatsyshyn; P. Bruzdziak; J. Namiesnik; O. Shyshchak

doi:10.14314/polimery.2016.766

Published : 2021-01-24

Vol. 61 No. 11-12 (2016)

Synthesis and properties of carboxy derivative of Epidian 6 monomethacrylate

M. Bratychak O. Iatsyshyn P. Bruzdziak J. Namiesnik O. Shyshchak

DOI: https://doi.org/10.14314/polimery.2016.766

Abstract

We present the synthesis of an oligomer with carboxy and methacrylic groups based on Epidian 6. The effect of the catalyst nature and amount, solvent nature and process temperature on the rate of the reaction between Epidian 6 monomethacrylate and adipic acid was examined at 313, 323 and 333 K in the presence of 4-dimethylaminopyridine, 1,4-diazobicyclo[2.2.2]octane, and benzyltriammonium chloride. The synthesized oligomer was characterized using chemical and IR-spectroscopic analyses. We suggest the use of the synthesized product as an active additive to epoxy-oligoesteric blends based on Epidian 5. The chemistry of the film forming process has been determined using IR-spectroscopy.

Keywords

epoxy resin ; adipic acid ; carboxy group ; methacrylic group ; crosslinking ; gel-fraction ; infrared spectroscopy żywica epoksydowa ; kwas adypinowy ; grupa karboksylowa ; grupa metakrylowa ; sieciowanie ; frakcja żelowa ; spektroskopia IR

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Bratychak, M., Iatsyshyn, O., Bruzdziak, P., Namiesnik, J., & Shyshchak, O. (2021). Synthesis and properties of carboxy derivative of Epidian 6 monomethacrylate. Polimery, 61(11-12), 766–772. https://doi.org/10.14314/polimery.2016.766

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M. Bratychak mbratych@polynet.lviv.ua

Affiliation
Lviv Polytechnic National University, Department of Petroleum Chemistry and Technology, 12 Bandera Street, 79-013 Lviv, Ukraine

O. Iatsyshyn

Affiliation
Lviv Polytechnic National University, Department of Petroleum Chemistry and Technology, 12 Bandera Street, 79-013 Lviv, Ukraine

P. Bruzdziak

Affiliation
Gdansk University of Technology, G. Narutowicza 11/12, 80-233 Gdansk, Poland

J. Namiesnik

Affiliation
Gdansk University of Technology, G. Narutowicza 11/12, 80-233 Gdansk, Poland

O. Shyshchak

Affiliation
Lviv Polytechnic National University, Department of Petroleum Chemistry and Technology, 12 Bandera Street, 79-013 Lviv, Ukraine