Hybrid polymer containing ferric oxides obtain using a redox polymer. Part II. Sorption properties towards chromate

I. Jacukowicz-Sobala; A. Ciechanowska; E. Kociołek-Balawejder

doi:10.14314/polimery.2014.213

Published : 2014-03-30

Vol. 59 No. 3 (2014)

Hybrid polymer containing ferric oxides obtain using a redox polymer. Part II. Sorption properties towards chromate

I. Jacukowicz-Sobala A. Ciechanowska E. Kociołek-Balawejder

DOI: https://doi.org/10.14314/polimery.2014.213

Abstract

In this work a hybrid material containing iron oxide was used as an effective sorbent for removal of Cr(VI) from water solutions. The hybrid sorbent was obtained by new method using redox S/DVB copolymer containing N-chlorosulfonamide functional groups in reduction/oxidation reaction with Fe(II) ions. The obtained product contained sulfonamide functional groups which are not charged in wide pH range (till pH = 11.0), what differs our product from other polymeric hybrid sorbents with iron oxide reported in the literature and obtained on the basis of ion exchangers. The sorption kinetic data were well described by pseudo-second order model indicating the chemisorption of chromate onto iron oxide surface. These data also correlated well with intraparticle diffusion model, what showed that diffusion within the polymer structure was the rate determining step of the chromate sorption process. The equilibrium studies showed that removal of Cr(VI) was pH dependent and was favored under acidic conditions (pH = 2.5—5.0). After adsorption process chromates were effectively desorbed from the adsorbent surface by NaOH solution.

Keywords

hybrid polymers ; iron oxides ; nanocomposites ; chromate adsorption polimery hybrydowe ; tlenki żelaza ; nanokompozyty ; adsorpcja chromianów

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Jacukowicz-Sobala, I., Ciechanowska, A., & Kociołek-Balawejder, E. (2014). Hybrid polymer containing ferric oxides obtain using a redox polymer. Part II. Sorption properties towards chromate. Polimery, 59(3), 213–219. https://doi.org/10.14314/polimery.2014.213

References

Hyatt A., Hart J. A., Brown S., Simon M., Latuzt N., Jacobs A., Guertin J.: “Chromium(VI) waste stream processing”, in: “Chromium(VI) Handbook” (Ed., Guertin J., Jacobs J. A., Avakian C.P.), CRC Press Washington DC 2005, p. 465—489.

[2] Hawley E.L., Jacobs J.A.: “Chromium: policy and regulations” in: “Chromium(VI) Handbook” (Ed., Guertin J., Jacobs J.A., Avakian C.P.), CRC PressWashington DC 2005, p. 491—521.

[3] Jacukowicz-Sobala I.: Przem. Chem. 2009, 88, 51.

[4] Owlad M., Aroua M.K.,Wan DaudW.A., Baroutian S.: Water Air Soil Pollut. 2009, 200, 59, http://dx.doi.org/10.1007/s11270-008-9893-7

[5] Mohan D., Pittman C.U.Jr: J. Hazard. Mater. 2006, B137, 762, http://dx.doi.org/10.1016/j.jhazmat.2006.06.060

[6] Sen M., Ghosh Dastidar M.: Iran J. Environ. Health Sci. Eng. 2010, 7, 182.

[7] Fendorf S., Eick M.J., Grossl P., Sparks D.L.: Environ. Sci. Technol. 1997, 31, 315, http://dx.doi.org/10.1021/es950653t

[8] He Y.T., Traina S.J.: Environ. Sci. Technol. 2005, 39, 4499, http://dx.doi.org/10.1021/es0483692

[9] Hu J., Lo I.M.C., Chen G.: Sep. Purif. Technol. 2007, 56, 249, http://dx.doi.org/10.1016/j.seppur.2007.02.009

[10] Wang P., Lo I.M.C.: Water Res. 2009, 43, 3727, http://dx.doi.org/10.1016/j.watres.2009.05.041

[11] Cumbal L.H., SenGupta A.K.: Ind. Eng. Chem. Res. 2005, 44, 600, http://dx.doi.org/10.1021/ie040126v

[12] Cumbal L.H., SenGupta A.K.: Environ. Sci. Technol. 2005, 39, 6508, http://dx.doi.org/10.1021/es050175e

[13] DeMarco M.J., SenGupta A.K., Greenleaf J.E.: Water Res. 2003, 37, 164, http://dx.doi.org/10.1016/S0043-1354(02)00238-5

[14] Pan B., Qiu H., Pan B., Nie G.: Water Res. 2010, 44, 815, http://dx.doi.org/10.1016/j.watres.2009.10.027

[15] Blaney L.M., Cinar S., SenGupta A.K.: Water Res. 2007, 41, 1603, http://dx.doi.org/10.1016/j.watres.2007.01.008

[16] Hristovski K., Wasterhoff P., Moller T., Sylvester P.: J. Hazard. Mater. 2008, 152, 397, http://dx.doi.org/10.1016/j.jhazmat.2007.07.016

[17] Iesan C.M., Capat C., Ruta F., Udrea I.: Water Res. 2008, 42, 4327, http://dx.doi.org/10.1016/j.watres.2008.06.011

[18] Iesan C.M., Capat C., Ruta F., Udrea I.: React. Funct. Polym. 2008, 68, 1578, http://dx.doi.org/10.1016/j.reactfunctpolym.2008.08.011

[19] Sarkar S., Blaney L.M., Gupta A., Ghosh D.: React. Funct. Polym. 2007, 67, 1599, http://dx.doi.org/10.1016/j.reactfunctpolym.2007.07.047

[20] Pat. USA 7 291 578 B2 (2004).

[21] Sheha R.R., El-Zahhar A.A.: J. Hazard. Mater. 2008, 150, 795, http://dx.doi.org/10.1016/j.jhazmat.2007.05.042

[22] Jacukowicz-Sobala I., Ciechanowska A., Kocio³ek-Balawejder E.: Polimery 2014, 59, 131.

[23] HermanowiczW., Dojlido J., Do¿añskaW., Koziorowski B., Zerbe J. „Fizyko-chemiczne badanie wody i ścieków”, Arkady, Warszawa 1999.

[24] Ho Y.S.: Scientometrics 2004, 59, 171.

[25] Ho Y.S., McKay G.: Adsorp. Sci. Technol. 1998, 16, 243.

[26] Ho Y.S., Ofomaja A.E.: J. Hazard. Mater. 2006, B129, 137, http://dx.doi.org/10.1016/j.jhazmat.2005.08.020

[27] Sutherland C., Venkobachar Ch.: Int. Res. J. Plant Sci. 2010, 1, 107.

[28] Cornell R.M., Schwertmann U.: “The iron oxides — structure, properties, reactions, occurrences and uses”,Wiley—VCH, Weinheim 2003.

[29] Qiu H., Lv L., Pan B., Zhang Q.: J. Zhejiang Univ. Sci. 2009, A10, 716, http://dx.doi.org/10.1631/jzus.A0820524

[30] Peak D., Ford R.G., Sparks D.L.: J. Colloid Interf. Sci. 1999, 218, 289, http://dx.doi.org/10.1006/jcis.1999.6405

Google Scholar

Altmetric indicators

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

I. Jacukowicz-Sobala polimery@ichp.pl

Affiliation
Wrocław University of Economics, Department of Industrial Chemistry, ul. Komandorska 118/120, 53-345 Wrocław, Poland

A. Ciechanowska

Affiliation
Wrocław University of Economics, Department of Industrial Chemistry, ul. Komandorska 118/120, 53-345 Wrocław, Poland

E. Kociołek-Balawejder

Affiliation
elzbieta.kociolek-balawejder@ue.wroc.pl