Silanowe środki wiążące. Cz. IX. Epoksyfunkcyjne karbosilany

H. Maciejewski; I. Dąbek; B. Marciniec

Published : 2022-09-01

Vol. 49 No. 10 (2004)

Silane coupling agents. Part IX. Epoxyfunctional carbosilanes

H. Maciejewski I. Dąbek B. Marciniec

Abstract

Epoxyfunctional carbosilanes are a group of silane coupling agents, which because of their structures and properties are applied as crosslinking agents, adhesion promoters or modifiers of fillers and mineral surfaces. Methods of syntheses [equation (2) and (3)], properties and characteristics as well as main directions of applications of epoxyfunctional carbosilanes, especially 3-glicydoxypropyltrialkoxysilanes [Formula (I)] and beta-(3,4--epoxycyclohexyl)ethyltrialkoxysilanes [Formula (II)] have been presented. The first ones are used mainly as silane coupling agents while the other ones as modifiers of polymers. Technology, developed by authors, of 3-glicydoxypropyltriethoxysilane synthesis basing on catalytic process of allyl-glicydyl ether hydrosilylation is a base of this silane production at the UNISIL Co., Ltd. in Tarnów, Poland.

Keywords

epoksyfunkcyjne karbosilany ; karbosilany ; hydrosililowanie ; środki wiążące ; promotory adhezji ; czynniki sieciujące epoxyfunctional silanes ; carbosilanes ; hydrosilylation ; coupling agents ; adhesion promoters ; crosslinking agents

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Maciejewski, H., Dąbek, I., & Marciniec, B. (2022). Silane coupling agents. Part IX. Epoxyfunctional carbosilanes. Polimery, 49(10), 677–683. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1799

References

Kroschwitz J. L, Howe-Grant M. (redaktorzy): "Kirk-Othmer Encyclopedia of Chernical Technology", 4 wyd., Wiley, Nowy Jork 1997.

[2] Pluddemann E. P.: w "Silanes and Other Coupling Agents" (red. Mittal K. L.), VSP, Utrecht 1992, str. 3-19.

[3] Tesoro J. G., Wu Y.: w [2], str. 215-228.

[4] Pluddemann E. P.: "Silane Coupling Agents", wydanie 2., Plenum, Nowy Jork 1991.

[5] Culiński J., Maciejewski H.: Chemik 1998, 5, 119.

[6] Marciniec B., Culiński J., Mirecki J.: Polimery 1990, 35, 213.

[7] Marciniec B., Culiński J.: Polimery 1992, 37, 72.

[8] Marciniec B., Urbaniak W., Maciejewski H.: Polimery 1993, 38, 53.

[9] Marciniec B., Culiński J.: Polimery 1995, 40, 77.

[10] Marciniec B., Foltynowicz Z.: Polimery 1995,40, 144.

[11] Maciejewski H., Guliński J., Marciniec B.: Polimery 1998, 43, 75.

[12] Urbaniak W., Marcinlec B.: Polimery 1998,43,148.

[13] Maciejewski H., Culiński J., Marciniec B.: Polimery 1998, 43, 219.

[14] Materiały reklamowe firm Witco Corp., Shin Etsu, Degussa Huls, Power Chemical Corp.

[15] Pat. francuski 1 526231 (1968).

[16] Praca zbiorowa: "Comprehensive Handbook on Hydrosilylation" (red. Marciniec B.), Pergamon, Oxford 1992.

[17] Oijma I.: w "The Silieon Organic Chemistry" (red. Rappoport Z., Apoeloig Y.), J. Wiley & Sons, Chichester 1998.

[18] Marciniec B.: Silic. C/mn. 2002, l, 155.

[19] Marciniec B., Culiński J., Maciejewski H.: w "Encyclopedia of Catalysis" (red. Horvath 1.), J. Wiley & Sous, Nowy Jork 2003.

[20] Pat. europ. 288286 (1988).

[21] Pat. niem. 1 937904 (1970).

[22] Pat. niem. 1 259 887 (1968).

[23] Pat. europ. 277 023 (1988).

[24] Pat. jap. 2000128763 (2000).

[25] Pat. niem. 2 159 991(1973).

[26] Pat. USA 4 966 981 (1990).

[27] Pat. USA 5 986 124 (1999).

[28] Pat. USA 4804768 (1989).

[29] Pol. zgłosz. pat. 351449 (2001).

[30] Pat. europ. 262642 (1988).

[31] Pat. USA 6100408 (2000).

[32] Pat. USA 4 736 049 (1988).

[33] Polskie zgłosz. pat. 368 154 (2004).

[34] Pat. USA 5 155 233 (1992).

[35] Pat. jap. 2001 055487 (2001).

[3
Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0

H. Maciejewski metalorg@main.amu.edu.pl

Affiliation
Uniwersytet im. A. Mickiewicza, Wydział Chemii, ul. Grunwaldzka 6, 60-780 Poznań

I. Dąbek

Affiliation
Poznański Park Naukowo Technologiczny Fundacji UAM. Inkubator Technologii Chemicznych, ul. Rubież 46, 61-612 Poznań

B. Marciniec

Affiliation
Uniwersytet im. A. Mickiewicza, Wydział Chemii, ul. Grunwaldzka 6, 60-780 Poznań