Effect of thermal aging on the crystalline structure and mechanical performance of fully bio-based, furan-ester, multiblock copolymers

M. Kwiatkowska; I. Kowalczyk; A. Szymczyk; K. Gorący

doi:10.14314/polimery.2018.9.3

Published : 2021-01-13

Vol. 63 No. 9 (2018)

Effect of thermal aging on the crystalline structure and mechanical performance of fully bio-based, furan-ester, multiblock copolymers

M. Kwiatkowska I. Kowalczyk A. Szymczyk K. Gorący

DOI: https://doi.org/10.14314/polimery.2018.9.3

Abstract

In this study, the effect of thermal aging on the physical transitions, crystalline structure development and the mechanical performance of furan-ester, multiblock copolymers is reported. The materials were synthesized via polycondensation in a melt using 2,5-furandicarboxylic acid (FDCA), 1,3-propanediol (1,3-PD) and dimerized fatty acid diol (FADD). All reagents were plant-derived. The copolymers were characterized by a multiblock structure with randomly distributed poly(trimethylene 2,5-furandicarboxylate) (PTF) and FADD segments and a phase separation forced by the crystallization of the rigid segment. As a consequence, the copolymers revealed elastomeric behavior and a rubbery plateau over a relatively large temperature range and also good processability. However, due to the specific architecture of FDCA – the most important bio-based monomer – the crystallization of the rigid segment was impeded. Differential scanning calorimetry (DSC), wide-angle (WAXS) and small-angle X-ray scattering (SAXS) analyses confirmed a significant development in the crystalline structure due to the thermal treatment. As a consequence, noticeable changes in the mechanical performance of the copolymer samples were observed, which is interesting for potential applications of these new materials.

Keywords

2,5-furandicarboxylic acid ; furan-ester copolymers ; bio-based polymers ; thermal aging kwas 2,5-furanodikarboksylowy ; kopolimery furano-estrowe ; polimery otrzymane z monomerów pochodzenia roślinnego ; proces wygrzewania

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Kwiatkowska, M., Kowalczyk, I., Szymczyk, A., & Gorący, K. (2021). Effect of thermal aging on the crystalline structure and mechanical performance of fully bio-based, furan-ester, multiblock copolymers. Polimery, 63(9), 594–602. https://doi.org/10.14314/polimery.2018.9.3

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[7] Jacquel N., Freyermouth F., Fenouillot F. et al.: Journal of Polymer Science Part A: Polymer Chemistry 2011, 49, 5301. http://dx.doi.org/10.1002/pola.25009

[8] Siegenthaler K.O., Künkel A., Skupin G., Yamamoto M.: “Synthetic Biodegradable Polymers”, (Eds. Rieger B., Künkel A., Coates W.G., Reichardt R., Dinjus E., Zevaco A.T.), Springer, Berlin Heidelberg 2012, p. 91.

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[13] Bugnicourt E., Cinelli P., Lazzeri A. et al.: Express Polymer Letters 2014, 8, 791. http://dx.doi.org/10.3144/expresspolymlett.2014.82

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[17] Kowalczyk I., Kwiatkowska M., Rosłaniec Z.: Elastomery 2016, 20, 40.

[18] Kröger M., Prüße U., Vorlop K.-D.: Topics in Catalysis 2000, 13, 237.

[19] Pat. EU EP0356703A3 (1990).

[20] Pat. US 8748637B2 (2013).

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[53] Papageorgiou G.Z., Papageorgiou D.G., Tsanaktsis V. et al.: Polymer 2015, 62, 28. http://dx.doi.org/10.1016/j.polymer.2015.01.080

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M. Kwiatkowska magdalena.kwiatkowska@zut.edu.pl

Affiliation
West Pomeranian University of Technology, Institute of Material Science and Engineering, Piastów 19, 70-310 Szczecin, Poland

I. Kowalczyk

Affiliation
West Pomeranian University of Technology, Institute of Material Science and Engineering, Piastów 19, 70-310 Szczecin, Poland

A. Szymczyk

Affiliation
West Pomeranian University of Technology, Institute of Physics, Piastów 48, 70-310 Szczecin, Poland

K. Gorący

Affiliation
West Pomeranian University of Technology, Polymer Institute, Pułaskiego 10, 70-310 Szczecin, Poland