Synthesis and characterization of poly(vinyl alcohol-co-aspartic acid) copolymers

N. Tudorachi; R. Lipsa

Published : 2010-08-30

Vol. 55 No. 7-8 (2010)

Synthesis and characterization of poly(vinyl alcohol-co-aspartic acid) copolymers

N. Tudorachi R. Lipsa

Abstract

The study presents synthesis of vinyl alcohol and L-aspartic acid copolymers (PVA-co-Asp), by solution polycondensation procedure using manganese acetate as a catalyst. Two copolymers were obtained with molar ratio of poly(vinyl alcohol) (PVA) structural unit to aspartic acid equal to 10/0.5 and 10/1, respectively. PVA and copolymers were investigated using Fourier transform infrared spectroscopy (FT-IR), but copolymers also with nuclear magnetic resonance ( H NMR). Molecular weight (Mω) and limiting viscosity numbers ([η|] of these polymers were also determined. With a system for simultaneous thermogravimetric and differential scanning calorimetry analyses (TG-DSC) thermal stability of PVA and its copolymers was investigated and compared. There was also defined zeta potential of water dispersions of PVA and copolymers and also dimensions and polydispersity of copolymer particles.

Keywords

poli(alkohol winylowy) ; kwas L-asparaginowy ; usieciowane kopolimery ; stabilność termiczna poly(vinyl alcohol) ; L-aspartic acid ; crosslinked copolymers ; thermal stability

Details

References

Statistics

Authors

Download files

PDF

Zasady cytowania

Tudorachi, N., & Lipsa, R. (2010). Synthesis and characterization of poly(vinyl alcohol-co-aspartic acid) copolymers. Polimery, 55(7-8), 562–567. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1041

References

Finch C. A.: “Polyvinyl Alcohol”, John Wiley & Sons, Bristol, Great Britain 1973.

2. Aoi K., Takasu A., Okada M.: Macromol. Rapid Commun. 1975, 16, 757.

3. Aoi K., Takasu A., Okada M.: Macromolecules 1997, 30, 6134.

4. Aoi K., Takasu A., Tsuchiya M., Okada M.: Macromol. Chem. Phys. 1998, 199, 2805.

5. Takasu A., Aoi K., Okada M.: Macromol. Rapid Commun. 1997, 18, 497.

6. Gimenez A., Mantecon A., Ronda J. C., Cadiz V.: J. Appl. Polym. Sci. 1997, 65, 1643.

7. Tudorachi N., Lipsa R.: J. Optoelectron. Adv. Mater. 2006, 8, 659.

8. Tudorachi N., Lipsa R.: Materiale Plastice 2004, 41, No. 2, 99.

9. Tudorachi N., Lipsa R.: e-Polymers 2009, No. 122.

10. Tudorachi N., Lipsa R., Chiriac A.: COFrRoCA - Bacau, Romania, 22-26 September 2004, 141.

11. Hassan C. M., Peppas A.: Adv. Polym. Sci. 2000, 153, No. 41, 38.

12. Peppas N. A., Benner R. E.: Biomaterials 1980, 1, 158.

13. Tudorachi N., Lipsa R.: J. Optoelectron. Adv. Mater. 2007, 9, 952.

14. Elisseeff J., Anseth K., Langer R., Hrkach J. S.: Macromolecules 1997, 30, 2182.

15. Tomida M., Nakato T., Kuramochi M., Shibata M., Matsunami S., Kakuchi T.: Polymer 1996, 37, 4435.

16. Tomida M., Nakato T., Matsunami S., Kakuchi T.: Polimer 1997, 38, 4733.

17. Feng Y., Klee D., Hocker H.: Macromol. Chem. Phys. 2002, 203, 819.

18. Polaczek J., Dziki E., Pielichowski J.: Polimery 2003, 48, 61.

19. Tylek E., Polaczek J., Pielichowski J.: Polimery 2005, 50, 341.

20. Tubbs R. K.: J. Polym. Sci. A 1965, 3, 4181.

21. Koyama N., Doi Y.: Polymer 1997, 38, 1598.

22. Dumitru F.: “Practical Working of Biochemistry”, Romania, Bucharest 1977, p. 76.

Google Scholar

Citing articles via

Statistics

Total abstract views : 0

PDF Downloads : 0