Crosslinking polymerization of polyfunctional monomers by free radical mechanism

C. D. Vlad; S. Vasiliu

Published : 2010-03-30

Vol. 55 No. 3 (2010)

Crosslinking polymerization of polyfunctional monomers by free radical mechanism

C. D. Vlad S. Vasiliu

Abstract

The crosslinked architectures based on diallyl maleate (DAM) obtained by suspension polymerization techniques have been studied. The influence of synthesis parameters on the structure of poly(diallyl maleate) [poly(DAM)] and copolymers of DAM with methyl methacrylate (MM) [poly(DAM-co-MM)] was also investigated. The effect of the diluents (n-butyl acetate or cyclohexanole) on the inner macroporous structure (apparent and skeletal density, pore volume, total porosity, cyclohexane uptake) has been studied. The experimental results showed that the values of the solvent uptake are strongly influenced by the diluent quantity as well as its solubility parameter.

Keywords

sieciowanie ; polimeryzacja rodnikowa ; polimeryzacja suspensyjna ; maleinian diallilu ; metakrylan metylu ; kopolimer ; rozcieńczalnik ; porowatość crosslinking ; adical polymerization ; suspension polymerization ; diallyl maleate ; methyl methacrylate ; copolymer ; diluent ; porosity

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Vlad, C. D., & Vasiliu, S. (2010). Crosslinking polymerization of polyfunctional monomers by free radical mechanism. Polimery, 55(3), 181–185. Retrieved from https://polimery.ichp.vot.pl/index.php/p/article/view/1000

References

Dragan E. S., Dinu M. V., Vlad C. D.: /. Appl. Polym. Sci. 2003, 89, 2701.

2. Saha B., Streat M.: Ind. Eng. Chem. Res. 2005, 44, 8671.

3. Luca C., Maruta C., Bunia I., Urmenyi A. M., Sandu M., Rata D.: J. Appl Polym. Sci. 2005, 97, 930.

4. Gong B., Wang L., Wang C., Geng X.: J. Chromatogr. 2004, 1022, 33.

5. Liang Y. C., Svec R, Frechet J. M. J.: J. Polym. Sci., Part A: Polym. Chem. 1995, 33, 2639.

6. Maciejewska M., Osypiuk J., Gawdzik B.: J. Polym. Sci, Part A: Polym. Chem. 2005, 43, 3049.

7. Abrams I. M., Millar J. R.: React. Funct. Polym. 1997, 35, 7.

8. Fontanals N., Marce R. M., Galia M., Borruli F.: J.. Polym. Sci., Part A: Polym. Chem. 2003, 41, 1927.

9. Witek E.: Polimery 2008, 53, 477.

10. Grabowska B., Holzer M.: Polimery 2008, 53, 531.

11. Matsumoto A.: Prog. Polym. Sci. 2001, 26, 189.

12. Vlad C. D., Mihailescu S.: Eur. Polym. J. 2001, 37, 71.

13. Bouvier-Fontes L., Pirri R., Asua J. M., Leiza J. R.:J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 4684.

14. Zhong Y. B., Xue Z. W., Ming H. Z., Ren P. Z.: Eur. Polym. J. 2000, 36, 981.

15. Schildknecht C. E.: “Allyl Compounds and Their Polymers”, Wiley Interscience, New York 1973, p. 637-657.

16. Seidl J., Malinsky J., Dusek K., Heitz W: Adv. Polym. Sci. 1967, 5, 113.

17. Brtel E.: Przem. Chem. 1965, 44, 255.

18. Pepper K. W.: J. Appl. Chem. 1951, 1, 124.

19. Small P. E.: J. Appl. Chem. 1953, 3, 71.

20. Alfrey T., Lloyd W. G.: J. Polym. Sci. 1962, 62, 159.

21. Vlad C. D., Polinescu Ig., Barbu M.: Eur. Polym. J. 1994, 30, 863.

22. Polinescu Ig., Vlad C. D., Ioanid G.: Appl. Polym. Sci. 1996, 59, 991.

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