Polyoxazolines — mechanism of synthesis and solution properties

A. Dworak; B. Trzebicka; A. Kowalczuk; Ch. Tsvetanov; S. Rangelov

doi:10.14314/polimery.2014.088

Published : 2014-01-30

Vol. 59 No. 1 (2014)

Polyoxazolines — mechanism of synthesis and solution properties

A. Dworak B. Trzebicka A. Kowalczuk Ch. Tsvetanov S. Rangelov

DOI: https://doi.org/10.14314/polimery.2014.088

Abstract

Oxazolines and the mechanism of their polymerization have been known for over 40 years. The relatively easy control of the polymerization process of oxazolines, the wide range of oxazoline polymer properties, reaching from strongly hydrophilic through amphiphilic, temperature responding to strongly hydrophobic and last not least their high biocompatibility cause that these polymers are intensively studied and the interest for them seem to increase. In this paper the cationic polymerization of polyoxazolines, especially the problem of the reversible desactivation and reactivation of active centers, the self-organization and response to temperature changes of polyoxazolines is discussed basing upon own research and literature reports. The synthesis of nanocontainers based upon the thermoresponsivity of polyoxazolines for obtaining hollow nanoparticles in nanometer range is also described.

Keywords

oxazolines ; polymerization mechanism ; properties ; self-organization ; star polymers ; thermoresponsive polyoxazolines oksazoliny ; mechanizm polimeryzacji ; właściwości ; samoorganizacja ; polimery gwieździste ; termoczułe polioksazoliny

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Dworak, A., Trzebicka, B., Kowalczuk, A., Tsvetanov, C., & Rangelov, S. (2014). Polyoxazolines — mechanism of synthesis and solution properties. Polimery, 59(1), 88–94. https://doi.org/10.14314/polimery.2014.088

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A. Dworak andrzej.dworak@cmpw-pan.edu.pl

Affiliation
Polish Academy of Sciences, Centre of Polymer and Carbon Materials, PL-41-800 Zabrze, Poland

B. Trzebicka

Affiliation
Polish Academy of Sciences, Centre of Polymer and Carbon Materials, PL-41-800 Zabrze, Poland

A. Kowalczuk

Affiliation
Polish Academy of Sciences, Centre of Polymer and Carbon Materials, PL-41-800 Zabrze, Poland

Ch. Tsvetanov

Affiliation
Bulgarian Academy of Sciences, Institute of Polymers, 1113 Sophia, Bulgaria

S. Rangelov

Affiliation
Bulgarian Academy of Sciences, Institute of Polymers, 1113 Sophia, Bulgaria